HNRT 227 Fall 2015 Chapter 4 Heat and

HNRT 227 Fall 2015 Chapter 4 Heat and Temperature presented by Prof. Geller 10 September 2015 1

Do You Remember These? z Units of length, mass and time, and metric Prefixes z Density and its units z The Scientific Method z Speed, velocity, acceleration z Force z Falling objects z Newton’s Laws of Motion z Newton’s Law of Universal Gravity z Work z Potential Energy and Kinetic Energy z Conversion of Energy z Types/Sources of Energy 2

i. Clicker Question z. What is the result if you add 1015 to 1015? A 1015 B 1030 C 10150 D 1025 E 2 x 1015 3

i. Clicker Question z. Which unit of the following is the largest? A Kilometer B Astronomical Unit (AU) C Light Year (ly) D Gigameter 4

i. Clicker Question z. What is acceleration? A The change in distance per change in time. B The change in position per unit of time. C The ratio of the change in velocity per change in time. D The change of time per unit of length. 5

i. Clicker Question z What happens to the velocity and acceleration of an object in free fall? A The velocity decreases as the acceleration remains the same. B The velocity increases as the acceleration remains the same. C The velocity increases and the acceleration decreases. D The velocity increases and the acceleration increases. E Both velocity and acceleration decrease. 6

i. Clicker Question z. Neglecting air resistance, what are the forces acting on a bullet after it has left the barrel of a rifle? y. A y. B y. C y. D The force of air acting up and gravity acting down. Only the force of gravity acting straight down. There are no forces acting at this point. 7 All of the above are true.

Question for Thought z. A k. Whr is y. A y. B y. C y. D a unit of work a unit of energy a unit of power More than one of the above is true. z A k. Whr is a unit of work, and since energy is the ability to do work, it is also a unit of energy. In terms of units, a watt is a joule per second, and an hour, as a second, is a unit of time. The time units cancel, leaving a unit of a joule, which can be used to measure either work or energy. 8

Question for Thought z. What happens to the kinetic energy of a falling book when the book hits the floor? y. A y. B y. C The kinetic energy is destroyed. The kinetic energy is converted to heat only. The kinetic energy is converted to heat and sound. 9

z The magnitude of the force that a baseball player exerts with a 5 kilogram baseball bat on a 0. 2 kilogram ball is measured to be 50 Newtons. What is the magnitude of the force that the ball exerts on the bat? z A. 6 Newtons z B. 10 Newtons z C. 50 Newtons z D. 60 Newtons z E. 1. 0 Newtons 10

F 2 Box F 1 z In the diagram above, a box is on a frictionless horizontal surface with forces F 1 and F 2 acting as shown. If the magnitude of F 1 is greater than the magnitude of F 2, then the box is z A. moving at constant speed in the direction of F 1 z B. moving at constant speed in the direction of F 2 z C. accelerating in the direction of F 1 z D. accelerating in the direction of F 2 z E. not moving at all. 11

z When a satellite is a distance R from the center of Earth, the force due to gravity on the satellite is F. What is the force due to gravity on the satellite when its distance from the center of the Earth is 2 R? z A. 9 F z B. 4 F z C. F / 4 z D. F / 9 z E. F / 16 12

z Which of the following best describes the law of conservation of energy? z A. Energy must not be used up faster than it is created or the supply will run out. z B. Energy can be neither created nor destroyed. z C. Energy is conserved because it is easily destroyed. z D. Conservation is a law describing how to destroy matter. z E. Energy conservation is a law recently passed by Congress. 13

z. What is the power consumed by a 100 Joules energy source in 4 seconds? z. A. 400 Watts z. B. 100 Watts z. C. 200 Watts z. D. 50 Watts z. E. 25 Watts 14

Main Concepts for Chapter 4 z. Kinetic Molecular Theory z. Temperature z. Heat z. Phases of matter z. Thermodynamics 15

1 st Law of Thermodynamics z. In an isolated system, the total amount of energy, including heat energy, is conserved. z. ENERGY IS CONSERVED 16

Temperature z. A relative term reflecting how vigorously atoms in a substance are moving and colliding z. Alternative definition ythe average kinetic energy of the molecules in a region 17

Temperature z. Units y. Fahrenheit y. Celsius y. Kelvin z. Where is absolute zero? z. At what temperature does water freeze? Boil? 18

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Heat z. Heat is a form of energy ythe energy flows from a warmer object to a cooler object z. Units of heat ycalorie xamount of temperature needed to raise temperature of 1 gram of water 1 degree Celsius ykilocalorie (kcal or Calorie) xamount of temperature needed to raise temperature of 1 kg of water 1 degree Celsius 20

Specific Heat z. Ability of a material to absorb heat energy yproportional to mass yproportional to change in temperature z. Q = m*c*DT (note: not in textbook) yc is the SPECIFIC HEAT of the substance xamount of energy needed to increase temperature of 1 gram of substance 1 degree Celsius 21

Transfer of Heat z. Conduction y“movement of heat by collisions between vibrating atoms or molecules” z. Convection y“transfer of heat by the physical motion of masses” xcooler liquids or gasses descend while warmer liquids or gasses rise 22

Phases and Phase Diagram (NOT IN TEXT but IMPORTANT) 23

2 nd Law of Thermodynamics z. Two key components yheat flows from a warmer body to a cooler body yentropy increases remains constant or increases in time 24

Question for Thought z. Which is true about temperature and heat. y. A Temperature is a measure of the average kinetic energy of the molecules of a substance. y. B Heat is the total internal energy of the molecules involved in an energy transfer. y. C Both A and B above are true. y. D Neither A nor B above are true. 25

Question for Thought z As the temperature of a solid increases, the vibrations of the individual molecules become larger. When these vibrations become larger, the average distance between the molecules increases to accommodate these larger oscillations, and the solid expands. In a liquid or a gas, the individual molecules move faster as the temperature increases, and the collisions between individual molecules become more violent. Since the molecules are moving faster, they move farther apart as they travel a larger distance in the time between collisions. y. A This explains why most materials become less dense as their temperature is increased. y. B This explains why most materials become more dense as their temperature is increased. 26

Question for Thought z Would the tight packing of more insulation, such as glass wool, in an enclosed space increase or decrease the insulation value? y. A y. B Increase the insulation value. Decrease the insulation value. z Tight packing would tend to decrease the insulation value of glass wool because it would squeeze the wool together and give the heat more paths to travel. It is the presence of many small pockets of air, with unattached molecules, that gives glass wool and other similar insulation materials their insulating properties. 27

Question for Thought z A true vacuum bottle has a double-walled, silvered bottle with the air removed from the space between the walls. Describe how this design keeps food hot or cold by dealing with conduction, convection and radiation. z The vacuum between the walls prevents heat transfer by means of convection or conduction, while the silvered walls reflect radiated energy back into (or away from) the food, preventing energy transfer by radiation. 28

Question for Thought z. Cooler air is found in low valleys on calm nights. x. A True x. B False z True. Cooler air is denser than warmer air. This denser air weighs more per volume than the warmer air and pushes the warmer air out of the way as it sinks down to its lowest level. The warmer, less dense air sits on top of the cooler air because it weighs less per volume. 29

Question for Thought z. Is air a good insulator? y. A y. B Yes No z. Air is a good insulator because it is not very dense and conduction is not very efficient at transferring energy because the molecules are much farther apart than they are in solids or liquids. 30

Question for Thought z Can you explain the meaning of the mechanical equivalent of heat. z Mechanical energy can be converted to heat as it changes from external mechanical energy to the internal kinetic energy of the molecules. A given quantity of mechanical energy always yields a known amount of heat. 31

Question for Thought z. What do people really mean when they say that a certain food “has a lot of Calories”? z When people refer to the “Calorie content of food, ” they are referring to the amount of chemical energy available from the food. One way to measure the chemical energy of foodstuff is to find out how much heat is released by complete oxidation. A Calorie (kcal) is a measure of the heat release and thus is a 32 measure of the chemical energy released.

Question for Thought z. A piece of metal feels cooler than a piece of wood at the same temperature. y. A y. B True False z True. The metal is more efficient at conducting heat away from your hand than wood, so it feels cooler because your hand senses heat leaving your body. 33

Question for Thought z. Can you explain how latent heat of fusion and latent heat of vaporization are “hidden. ” z The latent heats of fusion and vaporization go into or are released from internal energy during a phase transition. There is no temperature change associated with these heat transfers, so they are 34 “hidden. ”

Question for Thought z. The condensation of water vapor on a bathroom mirror warms the bathroom. y. A y. B True False z True. Condensation occurs when more vapor molecules are returning to the liquid state than are leaving the liquid state. When a water vapor molecule joins a group of liquid water molecules, it has to give up its latent heat of vaporization. This heat is transferred to the surrounding air molecules such as the air in the bathroom. 35

Question for Thought z. Which provides more cooling for a styrofoam cooler? y. A y. B One with 10 pounds of ice at 0 degrees C One with 10 pounds of ice water at 0 degrees C? z The 10 pounds of ice (A) provide more cooling because as the ice undergoes the phase change into water, it absorbs heat. Ten pounds of ice water simply absorbs heat according to the value of its specific heat until it reaches room temperature and 36 therefore absorbs less heat.

Question for Thought z Consider that a glass filled with a cold beverage seems to “sweat. ” Would you expect more sweating inside a house during the summer or during the winter? y. A Summer y. B Winter z Water condenses out of the air onto the cooler surface of a glass because the air near the glass is cooled, lowering its temperature to the dew point. Since the warmer air can hold more water vapor in the summer, it would have more water vapor to condense. Therefore, you would expect more condensation in the summer. 37

Question for Thought z. A burn from steam at 100 degrees C is more severe than a burn from 100 degrees C water. y. A y. B True False z. True. One hundred degree Celsius steam contains more energy (540 cal/g) than 100°C water, so the steam burn would be more severe. 38

Question for Thought z Relative humidity typically increases after sunset. y. A y. B True False z True. Cooling of air reduces the capacity of air to hold water vapor. Relative humidity is a ratio of water in the air to how much water it can hold. Thus a decrease of capacity increases the relative humidity, even when the amount of water vapor in the air is constant. 39

Question z. A 1. 0 kg metal head of a geology hammer strikes a solid rock with a velocity of 5. 0 meters per second. Assuming that all of the energy is retained by the hammer head, how much will the temperature increase? (specific heat of hammer head is 0. 11 kcal/kg. C) 40

Answer 41

Question z. Lead is a soft, dense metal with a specific heat of 0. 028 kcal/kg. C, a melting point of 328. 0 o C and a heat of fusion of 5. 5 kcal/kg. How much heat must be provided to melt a 250. 0 kg sample of lead with a temperature of 20. 0 o C? 42

Answer 43