
30debb107a0b86a5ee7d00cb692c3f17.ppt
- Количество слайдов: 98
Company LOGO Air Pollution TREN 1 F 90 Sustainability, Environment and Tourism
Note worksheet Available for download at http: //www. brocku. ca/tren/courses/ tren 1 f 90
ap. lbl. gov/. . . /ELSI/Frames/pollution-main-f. html
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas • poisonous: ___________________________________
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas • poisonous: binds to hemoglobin and blocks oxygen transport to cells
Mode of action of CO Direct binding to hemoglobin molecules within red blood cells, upsetting cellular metabolism → disrupts oxygen and carbon dioxide transport Image credit: dept. physics. upen n. edu/. . . / subsection 1_1_3. html Hemoglobin molecule with carbon monoxide attached
Image copyright 2000 by Nucleus Communications, Inc. All rights reserved. http: //www. nucleusinc. com See “Why is Carbon Monoxide so Poisonous? ” at www. edinformatics. com/inter active_molecules/carbon_mo noxide. htm
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas • poisonous: binds to hemoglobin and blocks oxygen transport to cells • ____% comes from natural sources, especially from ______________
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas • poisonous: binds to hemoglobin and blocks oxygen transport to cells • 85 % comes from natural sources, especially from ______________
Major Air Pollutants Oxides of Carbon monoxide: • CO is a colourless, odourless gas • poisonous: binds to hemoglobin and blocks oxygen transport to cells • 85 % comes from natural sources, especially from oxidation of methane (marsh gas)
Major Air Pollutants Carbon monoxide: • human sources: _____________
Major Air Pollutants Carbon monoxide: • human sources: combustion of fuels
Major Air Pollutants Carbon monoxide: • human sources: combustion of fuels • human inputs insignificant on a global scale, but 95‑ 98% of CO levels in cities may come from this source, and CO levels may be 50‑ 100 times greater than worldwide averages
CO Concentrations in Ontario Geographical distribution of 1 hour maximum CO concentrations (ppm) across Ontario (1997) Source: Ministry of the Environment, 1999. Air Quality in Ontario – A Concise Report on the State of Air Quality in the Province of Ontario 1997. Canada.
Major Air Pollutants Carbon monoxide: • human sources: combustion of fossil fuels • human inputs insignificant on a global scale, but 95‑ 98% of CO levels in cities may come from this source, and CO levels may be 50‑ 100 times greater than worldwide averages • cigarette smoke contains 200‑ 400 ppm CO; ties up 5 ‑ 15 % of smoker's hemoglobin during smoking
Major Air Pollutants Carbon dioxide: • CO 2 is a normal component of atmosphere (currently about ______ ppm)
Major Air Pollutants Carbon dioxide: • CO 2 is a normal component of atmosphere (currently about 391 ppm) • average concentrations rising slowly due to ___________________
Major Air Pollutants Carbon dioxide: • CO 2 is a normal component of atmosphere (currently about 391 ppm) • average concentrations rising slowly due to burning of fossil fuels, destruction of forests
Major Air Pollutants Carbon dioxide: • CO 2 is a normal component of atmosphere (currently about 391 ppm) • average concentrations rising slowly due to burning of fossil fuels, destruction of forests • serious implications regarding global climate change via the "greenhouse effect"
Major Air Pollutants Oxides of sulphur Sulphur dioxide (SO 2) Sulphur trioxide (SO 3) • acrid, poisonous, corrosive gases • produced primarily by____________________________
Major Air Pollutants Oxides of sulphur Sulphur dioxide (SO 2) Sulphur trioxide (SO 3) • acrid, poisonous, corrosive gases • produced primarily by burning of high-sulphur fossil fuels (coal, oil) in industrial processes, thermal generators, and heating systems
Major Air Pollutants Oxides of sulphur • SO 2 reacts slowly in air to produce SO 3; SO 3 may react with water to form droplets of H 2 SO 4 (sulphuric acid) • dangerous to health when H 2 SO 4 and sulphate salt particulate pollution are inhaled together → synergistic effect greatly increases risk of lung cancer
bisulphite sulphur dioxide sulphuric acid ammonium sulfate
Major Air Pollutants Oxides of sulphur SO 2 emissions may be reduced by: 1. ___________________ 2. ___________________ 3. ___________________
Major Air Pollutants Oxides of sulphur SO 2 emissions may be reduced by: 1. Switching to low-sulphur fuels (< 1% sulphur) 2. ___________________ 3. ___________________
Major Air Pollutants Oxides of sulphur SO 2 emissions may be reduced by: 1. Switching to low-sulphur fuels (< 1% sulphur) 2. Processing fuels to reduce / remove sulphur 3. ___________________
Major Air Pollutants Oxides of sulphur SO 2 emissions may be reduced by: 1. Switching to low-sulphur fuels (< 1% sulphur) 2. Processing fuels to reduce / remove sulphur 3. Catalytic ‘scrubbing’ of exhaust or stack gases
Major Air Pollutants Oxides of Nitrogen Nitric oxide (NO) Nitrogen dioxide (NO 2) • NO formed in reaction between N and O at high temperatures in boilers, internal combustion engines, etc. • NO reacts slowly with ____and rapidly with _______ to form NO 2, a reddish‑brown gas with a pungent choking odour
Major Air Pollutants Oxides of Nitrogen Nitric oxide (NO) Nitrogen dioxide (NO 2) • NO formed in reaction between N and O at high temperatures in boilers, internal combustion engines, etc. • NO reacts slowly with oxygen and rapidly with ozone to form NO 2, a reddish‑brown gas with a pungent choking odour
Major Air Pollutants Oxides of Nitrogen • natural microbial action produces _______ times more NOx than human activities, but anthropogenic NOx is concentrated: urban NOx levels are ______ to ______ times greater than non‑urban atmospheres. • NO 2 is a_______________ and may damage plants
Major Air Pollutants Oxides of Nitrogen • natural microbial action produces about 10 times more NOx than human activities, but anthropogenic NOx is concentrated: urban NOx levels are ______ to ______ times greater than non‑urban atmospheres. • NO 2 is a_____ and may damage plants
Major Air Pollutants Oxides of Nitrogen • natural microbial action produces about 10 times more NOx than human activities, but anthropogenic NOx is concentrated: urban NOx levels are 10 to 100 greater than non‑urban atmospheres. times • NO 2 is a _____ and may damage plants
Major Air Pollutants Oxides of Nitrogen • natural microbial action produces about 10 times more NOx than human activities, but anthropogenic NOx is concentrated: urban NOx levels are 10 to 100 greater than non‑urban atmospheres. times • NO 2 is a lung irritant and may damage plants
http: //www. utoronto. ca/imap/collections/air_quality/ozone_ exceedance_gases. htm NOx Emissions in North America 1 x 1 degree Source: Canadian Global Emissions Interpretation Centre
Major Air Pollutants Oxides of Nitrogen • major threat is its role in the formation of ___________________ • may be controlled from chimneys by ______________________________________ • control in auto exhaust requires __________________
Major Air Pollutants Oxides of Nitrogen • major threat is its role in the formation of photochemical oxidants • may be controlled from chimneys by ______________________________________ • control in auto exhaust requires ____________
Major Air Pollutants Oxides of Nitrogen • major threat is its role in the formation of photochemical oxidants • may be controlled from chimneys by adjusting flame temperature and fuel delivery rates to ensure more complete combustion • control in auto exhaust requires ____________
Major Air Pollutants Oxides of Nitrogen • major threat is its role in the formation of photochemical oxidants • may be controlled from chimneys by adjusting flame temperature and fuel delivery rates to ensure more complete combustion • control in auto exhaust requires the use of catalytic converters
http: //www. utoronto. ca/imap/collections/air_quality/maps/Ontario-avg-NO 2. jpg Average NO 2 Concentrations in Ontario Source: MOE (1999)
Major Air Pollutants Hydrocarbons E. g. methane benzene butane propane Sources include: 1) ________________ 2) ________________ 3) ________________ • • involved in the production of _________________ some directly carcinogenic; most are highly reactive and do not persist for a long time
Major Air Pollutants Hydrocarbons E. g. methane benzene butane propane Sources include: 1) Incompletely- burned fuels 2) ________________ 3) ________________ • • involved in the production of _________________ some directly carcinogenic; most are highly reactive and do not persist for a long time
Major Air Pollutants Hydrocarbons E. g. methane benzene butane propane Sources include: 1) Incompletely- burned fuels 2) Solvent and fuel evaporation 3) ________________ • • involved in the production of _________________ some directly carcinogenic; most are highly reactive and do not persist for a long time
Major Air Pollutants Hydrocarbons E. g. methane benzene butane propane Sources include: 1) Incompletely- burned fuels 2) Solvent and fuel evaporation 3) Refinery emissions • • involved in the production of _________________ some directly carcinogenic; most are highly reactive and do not persist for a long time
Major Air Pollutants Hydrocarbons E. g. methane benzene butane propane Sources include: 1) Incompletely- burned fuels 2) Solvent and fuel evaporation 3) Refinery emissions • • involved in the production of photochemical smog some directly carcinogenic; most are highly reactive and do not persist for a long time
http: //www. utoronto. ca/imap/collections/air_quality/maps/dkgvocen. jpg
Major Air Pollutants Photochemical oxidants - secondary pollutants produced in the atmosphere by ____________________________________ - a complex mixture of reactive components including: 1) O 3 __________________ Effects: ______________________________________
Major Air Pollutants Photochemical oxidants - secondary pollutants produced in the atmosphere by reaction of NOx and hydrocarbons in the presence of sunlight - a complex mixture of reactive components including: 1) O 3 __________________ Effects: ______________________________________
Major Air Pollutants Photochemical oxidants - secondary pollutants produced in the atmosphere by reaction of NOx and hydrocarbons in the presence of sunlight - a complex mixture of reactive components including: 1) O 3 Ozone Effects: ______________________________________
Major Air Pollutants Photochemical oxidants - secondary pollutants produced in the atmosphere by reaction of NOx and hydrocarbons in the presence of sunlight - a complex mixture of reactive components including: 1) O 3 Ozone Effects: crop damage; rots rubber and plastics; throat irritation; fatigue; sterility
2) PAN _________________ Effects: ______________________________________ 3) R - C=O _______________ | H Effects: ______________________________________
2) PAN peroxyacetyl nitrates Effects: ______________________________________ 3) R - C=O _______________ | H Effects: ______________________________________
2) PAN peroxyacetyl nitrates Effects: damage to wild plants and to crops; irritation of eyes and mucous membranes 3) R - C=O _______________ | H Effects: ______________________________________
2) PAN peroxyacetyl nitrates Effects: damage to wild plants and to crops; irritation of eyes and mucous membranes 3) R - C=O aldehydes | H Effects: ______________________________________
2) PAN peroxyacetyl nitrates Effects: damage to wild plants and to crops; irritation of eyes and mucous membranes 3) R - C=O aldehydes | H Effects: eye, nose, throat irritation, coughing, wheezing, and bronchitis. Formaldehyde is considered a probable human carcinogen.
ammonia ammonium sulfate PHOTOCHEMICAL OXIDANTS: ozone Nitrogen dioxide Nitrous acid Nitric Acid Ethene, etc.
Particulates May be solids: • __________________________________ • __________________________________ • _________________
Particulates may be solids: • smoke • __________________________________ • __________________________________
Particulates may be solids: • smoke • soot • __________________________________ • _________________
Particulates may be solids: • smoke • soot • dust • __________________________________
Particulates may be solids: • smoke • soot • dust • asbestos • __________________________________ • _________________
Particulates may be solids: • smoke • soot • dust • asbestos • metallic particles • __________________________________
Particulates may be solids: • smoke • soot • dust • asbestos • metallic particles • sulphate salts • _________________
Particulates may be solids: • smoke • soot • dust • asbestos • metallic particles • sulphate salts • pollen
Particulates may be liquids: • __________________________________ • _________________
Particulates may be liquids: • oil sprays • __________________________________
Particulates may be liquids: • oil sprays • aqueous sprays • _________________
Particulates May be liquids: • oil sprays • aqueous sprays • solvent sprays
Particulates May be liquids: • oil sprays • aqueous sprays • solvent sprays • e. g. , ‘chemtrails’ from passenger jets
Particulates may be liquids: • oil sprays • aqueous sprays • solvent sprays Liquid droplets suspended in air: • _________________
Particulates may be liquids: • oil sprays • aqueous sprays • solvent sprays Liquid droplets suspended in air: • aerosols
Particulates Effects of particulates include: • __________________________________ • _________________
Particulates Effects of particulates include: • Damage to respiratory tract • __________________________________
Particulates Effects of particulates include: • Damage to respiratory tract • Synergistic effects on health (e. g. lung disease) • __________________________________ • _________________
Particulates Effects of particulates include: • Damage to respiratory tract • Synergistic effects on health (e. g. lung disease) • Damage to crops, wildlife, livestock • __________________________________
Particulates Effects of particulates include: • Damage to respiratory tract • Synergistic effects on health (e. g. lung disease) • Damage to crops, wildlife, livestock • Soiling and damage to materials • _________________
Particulates Effects of particulates include: • Damage to respiratory tract • Synergistic effects on health (e. g. lung disease) • Damage to crops, wildlife, livestock • Soiling and damage to materials • Microclimate effects, reduced visibility
Particulates Photochemical smog is a combination of : • Photochemical oxidants • __________________________________
Particulates Photochemical smog is a combination of : • Photochemical oxidants • Gaseous hydrocarbons • _________________
Particulates Photochemical smog is a combination of : • Photochemical oxidants • Gaseous hydrocarbons • Particulates
Company LOGO Controlling Air Pollution
Controlling air pollution • Technological approaches • Legislative approaches • Volunteer initiatives
Technological Approaches • • Catalytic converters Scrubbers Dust and particulate entrapment systems Activated carbon filters
Technological Approaches • Catalytic converters http: //static. howstuffworks. com/gif/ catalytic-converter-location. jpg
• Catalytic converters www. cateran. com. au/cateran/data. aspx
The Reduction Catalyst • first stage of the catalytic converter • uses platinum and rhodium to help reduce the NOx emissions • When an NO or NO 2 molecule contacts the catalyst, the catalyst rips the nitrogen atom out of the molecule and holds on to it, freeing the oxygen in the form of O 2. • The nitrogen atoms bond with other nitrogen atoms that are also stuck to the catalyst, forming N 2. For example: 2 NO => N 2 + O 2 or 2 NO 2 => N 2 + 2 O 2
The Oxidization Catalyst • second stage of the catalytic converter • reduces the unburned hydrocarbons and carbon monoxide by burning (oxidizing) them over a platinum and palladium catalyst • aids the reaction of the CO and hydrocarbons with the remaining oxygen in the exhaust gas. For example: 2 CO + O 2 => 2 CO 2
Scrubbers • air pollution control devices • air scrubbers, wet scrubbers, and gas scrubbers • use a high-energy liquid spray to remove aerosol and gaseous pollutants from an air stream • gases removed either by absorption or chemical reaction • may be used for process air cleansing and dust collection • commonly used to help control emissions of sulfur into the atmosphere See http: //process-equipment. globalspec. com/Learn. More/Manufacturing_Process_Equipment/Air_Quality/Scrubbers
Image source: http: //images. encarta. msn. com/xrefmedia/ aencmed/targets/illus/ilt/T 629102 A. gif
Dust filters • Use filter media and cyclonic action to trap dust and particulates in exhaust gases from industrial processes
Air Quality - Legislative approaches Federal: • Canadian Environmental Protection Act (CEPA): regulates air emissions on toxic substances through life cycle, fuels and fuel components, environmentally safe codes of practice, and control of transboundary air pollution, certain controlled substances (ozone depleting chemicals, asbestos, lead, mercury, vinyl chloride / PVC)
CEPA Regulations Part 7: Controlling Pollution and Managing Wastes • Division 4: Fuels (Sections 138 -148) - National fuel mark system • Division 5: Vehicle Engine and Equipment Emissions (Sections 149 -165) - transfers legislative authority from the Motor Vehicle Safety Act to CEPA. Generally speaking air, rail and marine engines are covered by the Aeronautics Act (R. S. C 1985, c. A-2), the Canada Transportation Act (S. C. 1996, c. 10) and the Canada Shipping Act (R. S. C. 1985, c. S-9) • Division 6: International Air Pollution (Sections 166 -174) • Division 8: Control of the Movement of Hazardous Waste and Recyclable Material and Prescribed Non-Hazardous Waste for Final Disposal (Sections 185 -192)
Air Quality - Legislative approaches • CCME / Environment Canada Management Plan for Nitrogen Oxides and VOCs (Nov 1990) to identify domestic emissions problems and ensure international compliance (see http: //www. atl. ec. gc. ca/epb/ccme/smog. html)
Air Quality - Legislative approaches Provincial Environmental Protection Act: • Ontario Regulation 419/05, Air Pollution - Local Air Quality • Decisions and Proposals for Individual Contaminants Drive Clean Program: vehicle emissions testing program to reduce smog and its harmful effects on the air (http: //www. ene. gov. on. ca/cons/371706. htm)
Air Quality – volunteer initiatives • Clean Air Day (05 June 2013) A day of celebration and awareness activities across the country to invite Canadians to take action on clean air and climate change. • One Tonne Challenge: Government of Canada challenges all Canadians to reduce our emissions of greenhouse gases by one tonne (or about 20%). • Consumer - Environmental Choice Program: helps consumers identify products and services that are less harmful to the environment, including air quality.
Air Quality – other initiatives • eco. ACTION programs: – eco. AUTO rebate program – eco. ENERGY home retrofit grants – eco. TRANSPORT municipal grants • Commuter Challenge
Air Quality – other initiatives • Energy Efficiency Participation Initiatives • Transportation Outreach • Residential Wood Heating Guide • Pesticide use guidelines • Citizen Monitoring of lichens (air quality indicators) under international Ecological Monitoring and Assessment Network (EMAN) protocols