234 th ACS National Meeting Boston, MA August 19 -23, 2007 Chemical Compliance Analytical System C-CAS Chemical Compliance Systems, Inc. 706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 973 -663 -2148 • (fax) 973 -663 -2378 www. chemply. com
“Smart” Inventory System Primary Databases Chemical Cross-Reference Dictionary Product Container Data Regulatory List of Lists Chemical Hazard Data (H/S/E “SMART” INVENTORY SYSTEM Additional Data & Criteria MSDS Index & Images CCS
Sample Chemical Cross-Reference Database CAS No. Name 3734 -97 -2 78 -53 -5 3734 -97 -2 106 -87 -6 101 -25 -7 78 -67 -1 80 -17 -1 CHKHZ 57 CHKHZ 9 5675 -7 87 -86 -5 7782 -50 -5 74 -87 -3 108 -90 -7 12789 -03 -6 75 -00 -3 3691 -35 -8 76 -06 -2 7647 -01 -0 1336 -36 -3 7782 -50 -5 12789 -03 -6 74 -87 -3 76 -06 -2 79 -11 -8 78 -95 -5 107 -14 -2 532 -27 -4 CHLOMYCOL CHLON CHLOOR (DUTCH) CHLOOR-METHAN (DUTCH) CHLOORBENZEEN (DUTCH) CHLOORDAAN (DUTCH) CHLOORETHAAN (DUTCH) CHLOORFACINON (DUTCH) CHLOORPIKRINE (DUTCH) CHLOORWATERSTOF (DUTCH) CHLOPHEN CHLOR (GERMAN) CHLOR KIL CHLOR-METHAN (GERMAN) CHLOR-O-PIC CHLORACETIC ACID CHLORACETONE (FRENCH) CHLORACETONITRILE CHLORACETOPHENONE CAS No. 78 -67 -1 CHIPMAN 6199 CHIPMAN 6200 CHIPMANR-6, 199 CHISSONOX 206 MONOMER CHKHZ 18 CAS No. 80 -17 -1 Synonyms 2, 2’-AZOBIS(2 -CYANOBUTANE) 2, 2’-AZOBIS(2 -METHYLPROPIONITRILE) 2, 2’-AZOBIS(ISOBUTYRONITRILE) 2, 2’-AZOBIS(2 -METHYLPROPANENITRILE) 2, 2’-AZODIISOBUTYRONITRILE 2, 2’-DICYANO-2, 2’-AZOPROPANE 2, 2’-DIMETHYL-2, 2’-AZODIPROPIONITRILE ACETO AZIB AIBN AIVN ALPHA, ALPHA’-AZOBIS(ISOBUTYRONITRILE) ALPHA, ALPHA’AZOBISISOBUTYLONITRILE ALPHA, ALPHA’-AZODIISOBUTYRIC ACID DINITRILE ALPHA, ALPHA’-AZODIISOBUTYRONITRILE AZDH AZDN Synonyms AZOBISISOBUTYLONITRILE BENZENESULFOHYDRAZIDE AZOBISISOBUTYRONITRILE BENZENESULFONIC ACID, HYDRAZIDE AZODIISOBUTYRONITRILE BENZENESULFONIC HYDRAZIDE AZODIISOBUTYRONITRILE (DOT) BENZENESULFONOHYDRAZIDE CHKHZ 57 BENZENESULFONYLHYDRAZINE GENITRON CELOGEN BSH GENITRON AZDN CHKHZ 9 GENITRON AZDN-FF GENITRON BSH N, N’-BIS(2 -CYANO-2 -PROPYL)DIAZENE HYDRAZIDE BSG PIANOFOR AN NITROPORE OBSH POLY-ZOLE AZDN PHENYLSULFOHYDRAZIDE POROFOR 57 PHENYLSULFONYL HYDRAZIDE POROFOR N POROFOR BSH POROPHOR N POROFOR CHKHZ 9 PROPANENITRILE, 2, 2’-AZOBIS(2 -METHYL)POROFOR-BSH-PULVER PROPIONITRILE, 2, 2’-AZOBIS(2 -METHYL)UN 2952 (DOT) VAZO 64 CCS
Sample Product Container Data BAR CODE LOCATION QUANTITY MANUFACTURER MFR. DATE RCVD. EXP. DATE TRADE NAME ITEM NO. UNIT OF ISSUE PHYSICAL STATE SIZE STORAGE CODE DISPOSAL CODE CCS
Sample of Regulated Chemical Lists A 1 C 1 D 1 ACGIH TLV Chemicals California—Title 22 Section 12201 Subdivision A USDOT Hazardous Materials—Title 49 CFR Part 172. 101 D 2 USDOT Optional Hazardous Materials—Title 49 CFR Part 172. 102 E 1 E 2 E 3 E 4 I 2 N 1 EPA: List of Extremely Hazardous Substances EPA: List of Toxic Chemicals Section 313 SARA EPA: List of Hazardous Substances and Reportable Quantities EPA: Hazardous Wastes from the P and U Lists IARC: Human Carcinogens NIOSH: Pocket Guide to Chemical Hazards N 3 NFPA 325 M N 4 O 1 O 2 O 3 O 4 O 5 P 1 S 2 NTP: 4 th Annual Report on Carcinogens OSHA: Table Z-1 OSHA: Table Z-2 OSHA: Table Z-3 OSHA: Table Z-4 OSHA: Human Carcinogens NJDEP Prohibited and Restricted Use Pesticide List Alaska: Designated Toxic and Hazardous Substances California: Permissible Exposure Limits for Chemical Contaminants 78 -67 -1 S 3 Florida Substance List S 4 S 5 Illinois Toxic Substance List Kansas: Section 302/313 Chemical List SB S 6 Massachusetts Substance List S 7 S 8 Minnesota List of Hazardous Chemicals Missouri: Employer Information-Toxic Substance List S 9 New Jersey: Right to Know Hazardous Substance List SA North Dakota: List of Hazardous Chemicals and Reportable Quantity SB Pennsylvania: Hazardous Substance List SC SD SE SF Rhode Island: Hazardous Substance List Texas: Hazardous Substance List West Virginia: Hazardous Substance List Wisconsin: Toxic and Hazardous Substances S 3 N 3, S 6 D 2, S 9 CCS
Sample of Regulated Chemical Lists Content American Conference of Governmental Industrial Hygienists (ACGIH) TLVs & BEIs CAS No. : Chemical Name: Primary: 1998 ADOPTION: Change notice: Adopted value: TWAppm: TWAmg/m 3: STELppm: STELmg/m 3: CEILppm: CEILmg/m 3: Skin Notation: Carcinogen Cat. : BEI: Molecular Weight: TLVBASIS: LISTID: UTIL: COMMENTS: 75 -07 -0 Acetaldehyde X (OSHA 200) (OSHA 360) 25 45 A 3 44. 05 Irritation 001 F DOT Hazardous Material Table 49 CFR 172. 101 CASNO: CHEMNAME: Shipping Name: Symbols: Hazard Class: ID No. : Packing Group: Label Codes: Special: Exceptions: Non. Bulk: Passenger: Cargo: Vessel Stowage Loc: Other: LISTID: UTIL: COMMENTS: 75 -07 -0 Acetaldehyde 3 UN 1089 I FLAMMABLE LIQUID A 3, B 16, T 20, T 26, T 29 one 201 243 Forbidden 30 L E 025 F CCS
Comprehensive Chemical Hazard Evaluation Criteria ACUTE HEALTH LD 50 (O/D) S/E Irritation p. H TLV FIRE Vapor Density Boiling Point CHRONIC HEALTH LC 50 Stench IDLH PEL Carcinogenicity Reproduction Effects Organ Effects (Neurotoxicity) Bioconcentration Factor SPECIAL Radioactive Water Reactive Oxidizer Corrosive REACTIVITY (NFPA) Explosivity Shock Sensitivity Stability Heat/Pressure Sensitivity ENVIRONMENTAL (AIR-WATER-SOIL) Vapor Density Odor Index Fish LD 50 Specific Gravity Volatilization Vapor Pressure Water Solubility Adsorptivity Biological Exposure Index Biological Oxygen Demand (BOD) Chemical Oxygen Demand (COD) Total Oxygen Demand (TOD) Persistence Groundwater Mobility Factor Hydrolysis Ambient Aquatic Life Advisory Concentration -AALAC Photolysis Maximum Contaminant Level-MCL Biodegradation Maximum Contaminant Goal-MCLG CCS
Complex & Confusing “Green” Criteria Options PHYSICAL/ CHEMICAL Kow LEL UEL Flashpoint Acute Vapor Pressure Neurotoxins LD 50 Inhalation Solubility Cancer Chronic Specific Gravity STEL Irritants Teratogens Henry’s Law Poisons TLV Organ Effects REL Sensitizers Mutagenicity HEALTH Endocrine Disrupters “Green” Criteria Options ? ECOLOGICAL Soil Water Persistence Exposure BCF Toxicity Long-Term Air REGULATIONS Federal State Int’l Environmental Health Safety SAFETY Research Corrosives Explosion Water Oxidizers Reactive Fire Customer CCS
Integrated Biobased Score Scheme (BBP-CAS) Regulated under Air REGULATORY SCORE Regulated under Water Regulated under Soil (0 -100%) _____% A. W. Regulated under Human Health Regulated under Safety FINAL BIOBASED GRADE (0 - 100%) Plant Score Grains Other Agricultural Aquatic Grasses _____% Animal Score Parts Fats, Oils, Greases Residues Wood Waste Animal Waste Plant Waste Marine Waste A. W. ECONOMIC PERFORMANCE SCORE First Cost A. W. Costs for Purchase Installation/Preparation Product Manufacture Future Cost Maintenance Repair Replacement Residual Value Life Cycle Cost Environmental Health Safety Regulatory Biomass (0 -100%) _____% Availability Renewability Performance Jobs Savings Parts Residues Waste Score (0 -100%) Forest Score Marine Score BIOMASS SCORE Wood Residues Fibers Residues CCS
Integrated Biobased Score Scheme (BBP-CAS) Air Score Persistence Exposure Toxicity Long-Term Effects Water Score Persistence Exposure Toxicity Long-Term Effects Soil Score Persistence Exposure Toxicity Long-Term Effects ECOLOGICAL SCORE (0 -100%) _____% A. W. FINAL BIOBASED GRADE (0 - 100%) HEALTH SCORE Acute Health Score Oral LD 50 Dermal LD 50 IDLH STEL/Ceiling Inhalation LC 50 Eye Irritation Odor Threshold Chronic Health Score Reproductive Effects Carcinogenicity Rf. C Rf. D Radioactivity Sensitizer Neurotoxicity TLV (0 -100%) _____% A. W. SAFETY SCORE (0 -100%) _____% A. W. Fire Score Special Score Reactivity Score TOXICITY - AIR (V. P. LC 50) BCF LONG-TERM EFFECTS - AIR Global Warming Potential Ozone-Depleting Potential Smog Acidification TOXICITY-WATER Fish LC 50 Daphae LC 50 Green Algae EC 50 (Solubility W-LC 50) BCF LONG-TERM EFFECTS - WATER Eutrophication Theoretical Oxygen Demand TOXICITY - SOIL (Koc O-LD 50) BCF 14 -day Worm LC 50 LONG-TERM EFFECTS - SOIL Groundwater Mobility Factor CERCLA RQ Flammability Radioactivity Oxidizer Water-Reactive Corrosive FLAMMABILITY Flash Point Boiling Point Explosivity CCS
MSDS No. 4 Centari® Acrylic Enamel Tints and Miscellaneous Factory Packaged Colors SECTION 2. COMPOSITION INFORMATION ON INGREDIENTS 1, 2, 4 -trimethyl benzene 2, 2, 4 -trimethyl-1, 3 -pentanediol monoisobutyrate 2, 2, 4 -trimethylpentane CAS # 95 -63 -6 25265 -77 -4 VAPOR PRESSURE 7. 0@44. 4°C 0. 0 EXPOSURE LIMITS A 25. 0 ppm, O 25. 0 ppm A None, O None 540 -84 -1 None A 300. 0 ppm, O 500. 0 ppm SECTION 3. HAZARDS IDENTIFICATION Other Potential Health Effects in addition to those listed above: ACETONE The following medical conditions may be aggravated by exposure: lung disease, eye disorders, skin disorders. Overexposure may cause damage to any of the following organs/systems: blood, central nervous system, eyes, kidneys, liver, respiratory system, skin. SECTION 11. ADDITIONAL INFORMATION 767 A™ Acrylic polymer-B, Alkyd resin, Aromatic hydrocarbon-A, Azxo yellow pigment, Butyl acetate, Ethylbenzene(2. 1 -5. 2%*@), Methyl ketone, Naphthalene(0. 0 -0. 2%*@), Toluene(12 -12%*@), Vm&p naphtha, Xylene(16 -19%*@) GAL WT: 8. 20 WT PCT SOLIDS: 46. 82 VOL PCT SOLIDS: 37. 99 SOLVENT DENSITY: 7. 02 VOC LE: 4. 4 VOC AP: 4. 4 FLASH POINT: 20°F to below 73°F H: 2 F: 3 R: 0 OSHA STORAGE: 1 B TSCA STATUS: In Compliance PHOTO-CHEMICALLY REACTIVE: YES No 817 A Listed CCS
The CCS Relational Chemical & Product Database (R-CPD) Product Descriptions Product Components MSDS Images MSDS Index Generic Categories Manufacturers User Director Processes Green Ratings Corrosive Ratings Biobased Ratings CCS Centralized Database COMMERCIAL PRODUCTS MUNITIONS – MIDAS CHEMICAL AGENTS Cross-Reference Dictionary Chemical Compound Dictionary Chemical Alternatives Toxicology Data Holistic Hazard Ratings Personal Protective Equipment SAF-T-LABEL© Safe Storage Codes Safe Disposal Codes Alloy Constituents Emergency Response Elemental Composition Incompatibilities Physical/Chemical Parameters AGENT SIMULANTS Munitions Characterization—MIDAS Demil Processes Constituent Chemicals Released Green Criteria Insensitive Criteria Corrosive Criteria Packaging Criteria Transportation/Storage Factors Reliability Factors Hazardous Waste Forms Regulations Properties Toxicology Data Hazard Issues Incompatibilities Storage Recommendations TICs/TIMs SECURITY FACTORS RADIOISOTOPES BIOTERRORISM AGENTS REGULATIONS 20+ Agents Disease Descriptors Pathogenesis Prophylaxis Emergency Response Decontamination Treatment 650 Total Regulations Local State Federal International Non-government Corporate or Trade Association Chemical Security Risk List Precursor Chemical Security Risk List Theft & Population Risks Accessibility Factors Generic Families Properties Effects & Actions Storage & Security Diagnosis & Treatment Decontamination Emergency Response CCS
C-Ho. SS Generic Chemical Hazard Classes • • • Explosives Chemical Agents Extreme Toxins Neurotoxins Radioactives Corrosives • • • Flammables Water Reactives Oxidizers Persistent Bioaccumulative Toxins Priority Pollutants Hazardous Air Pollutants CCS
Hazard Class Ranking Data Elements PROPERTIES — Structure — Chemical — Physical TOXICOLOGY DATA — Human — Animal — In Vitro HAZARDS INCOMPATIBILITIES — Protection — Decontamination — Persistence — Use — Chemical — Conditions — Containers a STORAGE RECOMMENDATIONS — Container — Conditions — Distances — HSASa Variables HSAS = Homeland Security Advisory System CCS
Incompatible Chemical Database (CCS Published Book) CHEMICAL CLASS CHEMICAL INCOMPATIBLE CHEMICAL I. C. CLASS INTERACTION HAZARD Corrosives Acetic Acid Nitric Acid Chlorine Hydrogen Peroxide Acetylene Aluminum Powder Oxidizer Flammable Metal Explosion Spontaneous Fire Flammables Acetone Benzene Carbon Disulfide Chloroform Chlorine Potassium Carcinogen Corrosive Flammable Explosion Violent Explosion Reactives Nitrotoluene Nitroethane Acrylonitrile Sulfuric Acid Hydrocarbons Bromine Corrosive Combustible Corrosive Explosion Products Toilet Bowl Cleaner Bleach Paint Solvent Metal Powders Ammonia Chloroform Metals Product Carcinogen Explosion Poisonous Gas Explosion CCS
Regulated Hazardous Chemicals Acute Hazard Orientation Chemical Agents Neurotoxins Extreme Toxins Radioactives Explosives Shock Sensitives Corrosives Flammable Oxidizers Hazardous Air Pollutants Persistent Bioaccumulative Toxins Priority Pollutants ACGIH Chemical Security Risks List DEA DOT EPA OSHA California Iowa Maryland Nevada New Jersey European Community CCS
CPSC Specialty Regulated Substances Canada Export Control Lists DEA Essential Chemicals DEA Precursor Chemicals DOC Export Restrictions EU Black/Gray Lists IATA Air Transport Forbidden Precursor Chemical Security Risks List IATA Passenger Transport Forbidden IATA Regulated Substances UK The Red List (Water) UN/FAO Prior Informed Consent CCS
Chemical Compliance Analytical System (C-CAS) Product Desc. Mfr. Table NSNs Locations Automated Usage Scales Local Data Mfr. Date Received Exp. Date Item Index Location Area Inventory Container Bar Code Quantity Process Data Cont. & Storage Codes Process Codes C-CAS Manufacturing Data Acquisition Module Master Inventory Reference Data MSDS Index MSDS Images Bar Code Master Chemical Reference Data C-CAS Web Server Components Unit of Issue Storage Code Physical State Manufacturer Synonym/ CAS # Dictionary Label Placard User ID Location Container Bar Code Type of Generation Waste Code Generic Dictionaries Waste Process Quantity Locat. EPA OSHA DOT NRC Regulatory Impact Analyses State Int'l. Storage Combination Regulations Carcin. Terato. Spill Neurot. Health Hazards Exting. Physical Hazards Physical Data Environ. Hazards Air, Water, Soil Data Specific Hazards TLVs Energy Recycled C-CAS Waste Module PELs Environmental Safety & Health Analyses Combination Hazards Disposed (multiple locations) Dispose Waste Profile Treated C-CAS Site Data Acquisition Module Activity/Tenant Analyses Manifest List of Lists Product Transaction & Cumulative Chemical Database with Local, Standardized Materials Management Analyses Prods. PPE Chemical Hazard Rating Trade Name Item Number Units Mfrs. Hierarchical Materials Management Analyses Specific Regulations Container Data Size Totals Chems. User Bar Code Disposal Code Product Comp. Procurement Analyses Special Hazards Oxydizers, Radioactives, H 2 O-Reacts. C-CAS Centralized Database Module Acute Chronic Flam. Explos. Corros. C-CAS Analytical Report Module CCS
Centralized Chemical Hazard and Environmental Management Suite (C-CHEMS) Centralized and Relational Databases Industrial Hygiene (IH-CAS) Locations & Types Processes, Test Results Natural Resources Chemical Tracking (C-CAS) or Existing System Chemicals/Products MSDS Images/Index, Location Air (A-CAS) Hazards, Incompatibilities, Storage Cultural Resources CCS Centralized Database Permits, Processes, Test Results Chemical Safety (CS-CAS) ) Commercial Products INRM Plan, NEPA, AR-200 -3 Inventory, NEPA, Mitigation Plans Munitions (MACS) ) MIDAS Characterization Constraints. Dispositions Munitions – MIDAS Chemicals Green Products (GP-CAS) Green Munitions (GM-CAS) Chemical Agents Health Impact, Green Rating Site-Specific Agent Simulants Health Impact, Green Rating Site-Specific Security Factors Water (W-CAS) ) Wireless Communication Options Permits, Treatments Test Results Toxics (T-CAS) Locations & Types Inspections, Test Results Sensor Data Input Radioisotopes Bioterrorism Agents Regulations Secure Web Access Options Storage Tanks (ST-CAS) ) Types & History, Permits Inspection Criteria Biobased Products (BBP-CAS) Hazardous Waste (HW-CAS) Restoration Program Locations & Permits Schedules, Dispositions Pesticides (P-CAS) Soil GIS, NJAC 7: 14, CERCLA Permits, Schedules, Inspections Environmental Audits (E-CAS) Permits & Standards Evaluation Criteria, Checklists Solid Waste (SW-CAS) GIS Data Sources Locations & Types Schedules, Dispositions CCS
Chemical Homeland Security System (C-Ho. SS) Centralized and Relational Databases Chemical Tracking (C-CAS) or Existing System Industrial Hygiene (IH-CAS) Locations & Types Processes Test Results Air (A-CAS) Permits Processes Test Results Chemicals/Products MSDS Images/ Index Location CCS Centralized Database Chemical Safety (CS-CAS) Hazards Incompatibilities Storage Munitions (M-CAS) MIDAS Characterization Constraints Dispositions COMMERCIAL PRODUCTS MUNITIONS – MIDAS Water (W-CAS) Wireless Communication Options Permits Treatments Test Results CHEMICALS CHEMICAL AGENTS AGENT SIMULANTS Secure Web Access Options Storage Tanks (ST-CAS ) Types & History Permits Inspection Criteria SECURITY Factors Toxics (T-CAS) RADIOISOTOPES Hazardous Waste (HW-CAS) Locations & Types Inspections Test Results BIOTERRORISM Agents Locations & Permits Schedules Dispositions REGULATIONS Pesticides (P-CAS) Sensor Data Input Permits Schedules Inspections Solid Waste (SW-CAS) Product Security & Containment (PS-CAS) Chemical Risks Product Storage Codes Security Standards Locations & Types Schedules Dispositions GIS Data Sources CCS
MACS Integration Into Facility ISO 14001 EMS POLICY OBJECTIVES/ GOALS TARGETS/ REQUIREMENTS ASPECTS/ IMPACTS MANAGEMENT PROGRAM RESPONSIBILITIES SCHEDULE TRAINING DOCUMENTATION Multi-functional Do. D Green Procurement Program Fulfillment Munition/Nonmunition P 2 and Regulatory Compliance Munition/Nonmunition Security By Demil Operation By Specific Range & Operation For Procurement—Hazard Acquisition Constraints Security Incident Prevention C-Ho. SS Plasma Arc Feedrate Demil By Level, Function, Product Type & Restricted Constituents Within Permit Constraints By Demil/Range Operation & Regulation Storage Requirements by Area & Function Incinerator Feedrate Decrease/Increase Acquisition, Usage Releases, Exposures & Compliance Security Risks, Incidences, First Responder Analyses Chemical Tracking (NEW) Definable by Area, Level, Function, Process, Operation & Regulation Periodic Interim Status Reports By & Across Module(s) Integrated Documentation & Validation TRACS Hazardous Waste Simplified by Criteria, Pass/Fail Values Operation, Process & Area-Specific GP-CAS Green Nonmunitions Within Each Module Product & Constituent Data by Hazard, Area, Operation & Process Imaged Documents Decreased Incidence Likelihood & Severity MEASUREMENTS Within Each Module—Hazards & Compliance MANAGEMENT REVIEW C-CAS Risk Module Dispersion No Hierarchical Data Calls “Broad Picture” of Operations, Processes, Areas & Functions Integration of Munition, Nonmunition & Security Analyses & Compliance EMERGENCY PREPAREDNESS RECORDKEEPING MACS-1 Chemical Security (NEW) Within Each Module Annual Executive Review & Interim Detailed Reports MACS-3 Theoretical Compliance Analyses G-MACS Green Munitions MACS-2 (Ranges) CCS
For information, contact: Dr. George Thompson georgethompson@chemply. com 973 -663 -2148 Chemical Compliance Systems, Inc. 706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 973 -663 -2148 • (fax) 973 -663 -2378 www. chemply. com
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